The Evolution of 100-μm Aluminum Agglomerates and Initially Continuous Aluminum Particles in the Flame of a Model Solid Propellant. II. Results

摘要

A quenching/sampling method was used to study the evolution of monodisperse 100-μm aluminum agglomerates and continuous particles in the flame of combustion products — composite propellant at a pressure of 0.7-8 MPa. The particle residence time in the flame was varied in the range 6-170 msec, whereas the calculated time of their combustion was ≈25 msec. The evolution of a burning particle is related to the consumption of metallic aluminum and the deposition of oxide in the form of a cap, which, after complete combustion of aluminum, is transformed to the final spherical oxide particle. The density of the final oxide particles was measured. The ratio of the diameters and masses of the initial metal particle and the final oxide particles was determined. Data on particle fragmentation during combustion were obtained by comparing the numbers of the initial metal particles and the final oxide particles. Considerable differences in the combustion behavior of the agglomerates and continuous particles of size 100 μm were not found. It was established that the smaller the size of the burning particle the less oxide is deposited on the particle and the more oxide is carried away in the form of oxide smoke. For 100-μm particles, the fraction of deposited oxide was found to be ～0.1 of the total mass of oxide formed.