Density and excess properties of N-methyldiethanolamine (MDEA) with 1-hexyl-3-methylimidazolium tris(pentafluoroethyl)trifluorophosphate [hmim][FAP]

摘要

In the present work, new data on the densities and refractive indices for 1-hexyl-3-methylimidazolium tris(pentafluoroethyl)trifluorophosphate [hmim][FAP] with N-methyldiethanolamine are reported for various concentrations and at temperatures (303.15-328.15) K. Excess molar volumes and excess refractive indices were calculated from the experimental data. Refractive index values for the binary mixtures were predicted by using Lorentz-Lorenz, Gladstone-Dale and Eykman equations. Excess molar volumes showed positive trend, whereas excess refractive indices showed negative trend over the entire range of temperatures and concentrations studied in the present research.