Chromatographic Analysis of Polycyclic Arenes of Various Degree of Hydrogenation

摘要

The specificity of the intermolecular interaction of polycyclic arenes with the stationary phase under the conditions of HPLC is described most completely by multiple correlation equations that include first-to-fourth-order linear connectivity indices and the number of double bonds in molecules of polycyclic arenes as independent variables.The three-parameter equations can be used to predict the chromatographic behavior and standard-free identifications of polycyclic arenes in complex mixtures.