Trapping of Tricarbonyl(eta~2,eta~2-homoallyl)iron and Tricarbonyl(eta~3-ally)iron Anion Intermediates with 2-(Phenylsulfonyl)-3-phenyloxaziridine

摘要

The addition of reactive carbanions to (eta~4-1,3-diene)Fe(CO)_3 complexes at -78 deg C and 25 deg C produced putative homoallyl and allyl anion complexes,respectively.Reaction of the reaction intermediates with 2-(phenylsulfonyl)-3-phenyloxaziridine afforded nucleophilic substituted (eta~4-1,3-diene)Fe(CO)_3 complexes.