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首页> 外文期刊>Journal of Molecular Liquids >Localized and delocalized modes in the tangent-space dynamics of planar hard dumbbell fluids
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Localized and delocalized modes in the tangent-space dynamics of planar hard dumbbell fluids

机译:平面硬哑铃状流体切线空间动力学中的局部和离域模式

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摘要

Systems of hard dumbbells are, arguably, the simplest model for a molecular fluid composed of linear molecules. We study here the Lyapunov instability for two-dimensional systems containing qualitatively different degrees of freedom, translation and rotation. We characterize this instability by the Lyapunov spectrum, which measures the rate of exponential divergence, or convergence, of infinitesimal phase space perturbations along selected directions. We characterize the dependence of the spectrum and of the Kolmogorov-Sinai entropy on the density and on the dumbbell anisotropy, where the emphasis is on the thermodynamic limit. The phase space perturbation growing exponentially with a rate given by the maximum Lyapunov exponent is strongly localized in space, and this localization persists in the thermodynamic limit. The perturbations growing according to the smallest positive exponents, on the other hand, are represented by coherent wavelike structures spread out over the whole simulation box. Depending on the degeneracy of the associated exponents, these perturbations are either non-propagating transversal, or propagating longitudinal modes. Because of the analogy with the familiar hydrodynamic modes of continuum mechanics, the so-called Lyapunov modes promise to be of importance for understanding the dynamics of fluids and solids. [References: 41]
机译:硬哑铃系统可以说是由线性分子组成的分子流体的最简单模型。我们在这里研究二维系统的Lyapunov不稳定性,该系统包含定性不同的自由度,平移度和旋转度。我们用李雅普诺夫谱来表征这种不稳定性,该谱测量沿选定方向的无穷小相空间扰动的指数发散或收敛速率。我们刻画了光谱和Kolmogorov-Sinai熵对密度和哑铃各向异性的依赖性,其中重点是热力学极限。以最大李雅普诺夫指数给出的速率成指数增长的相空间扰动强烈地局限在空间中,并且这种局限持续存在于热力学极限中。另一方面,根据最小的正指数增长的扰动由分布在整个模拟框中的相干波状结构表示。取决于相关指数的简并性,这些扰动是非传播的横向模式或传播的纵向模式。由于与连续介质力学的熟悉的流体力学模式相似,因此所谓的Lyapunov模式有望对理解流体和固体的动力学具有重要意义。 [参考:41]

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