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Characterization of odor-active compounds of various cherry wines by gas chromatography-mass spectrometry, gas chromatography-olfactometry and their correlation with sensory attributes

机译:气相色谱-质谱,气相色谱-嗅觉法表征各种樱桃酒的气味活性化合物及其与感官属性的关系

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摘要

To characterize the aroma of cherry wine, five samples were analyzed by quantitative descriptive sensory analysis, gas chromatography-mass spectrometry (GC-MS) and gas chromatography-olfactometry (GC-O). The aroma of cherry wines was described by 6 sensory terms as fruity, sour, woody, fermentation, cameral and floral. Fifty-one odor-active (OA) compounds were detected by GC-O and quantified by GC-MS, and 45 of them were identified. Twenty-nine OA compounds having more than 50% detection frequency were selected as specific compounds correlated to sensory attributes by partial least squares regression (PLSR). The correlation result showed ethyl 2-methyl propionate, 2,3-butanedione, ethyl butyrate, ethyl pentanoate, 3-methyl-1-butanol, ethyl hexanoate, 3-hydroxy-2-butanone, ethyl lactate, 1-hexanol, (Z)-3-hexen-1-ol, ethyl hydroxyacetate, acetic acid, furfural, 2-ethyl-1-hexanol, benzaldehyde, propanoic acid, butanoic acid, guaiacol, beta-citronellol, hexanoic acid, 2-methoxy-4-methylphenol, 2-ethyl-3-hydroxy-4H-pyran-4-one, ethyl cinnamate, 2-methoxy-4-vinylphenol were typical OA compounds, which covaried with characteristic aroma of cherry wines.
机译:为了表征樱桃酒的香气,通过定量描述感官分析,气相色谱-质谱(GC-MS)和气相色谱-嗅觉法(GC-O)分析了五个样品。樱桃酒的香气通过6个感官术语描述为果味,酸味,木质味,发酵,照相和花香。通过GC-O检测了51种气味活性(OA)化合物,并通过GC-MS对其进行了定量,共鉴定出45种。通过偏最小二乘回归(PLSR)选择了检测频率超过50%的29种OA化合物作为与感觉属性相关的特定化合物。相关结果显示2-甲基丙酸乙酯,2,3-丁二酮,丁酸乙酯,戊酸乙酯,3-甲基-1-丁醇,己酸乙酯,3-羟基-2-丁酮,乳酸乙酯,1-己醇(( )-3-己烯-1-醇,羟基乙酸乙酯,乙酸,糠醛,2-乙基-1-己醇,苯甲醛,丙酸,丁酸,愈创木酚,β-香茅醇,己酸,2-甲氧基-4-甲基苯酚典型的OA化合物有2-乙基-3-羟基-4H-吡喃-4-酮,肉桂酸乙酯,2-甲氧基-4-乙烯基苯酚,它们与樱桃酒的特征香气有关。

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