Metal template effect on O-alkylation of tetrathiacalix[4]arene with 2-bromoacetamide to afford tetrakis(carbamoylmethoxy)thiacalix [4]arenes with cone and 1,3-alternate conformation

Rahman S; Shimizu T; Xi Z; Yamato T

首页> 外文期刊>Journal of Chemical Research. Synopses >Metal template effect on O-alkylation of tetrathiacalix[4]arene with 2-bromoacetamide to afford tetrakis(carbamoylmethoxy)thiacalix [4]arenes with cone and 1,3-alternate conformation

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Metal template effect on O-alkylation of tetrathiacalix[4]arene with 2-bromoacetamide to afford tetrakis(carbamoylmethoxy)thiacalix [4]arenes with cone and 1,3-alternate conformation

机译：金属模板对四硫杂杯[4]芳烃与2-溴乙酰胺的O-烷基化的影响，得到具有圆锥和1,3-交替构象的四（氨基甲酰基甲氧基）硫杂杯[4]芳烃

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Direct O-alkylation of tetrathiacalix[4]arene with 2-bromoacetamide afforded two conformational isomers (cone and 1,3-alternate) of tetrakis(carbamoylmethoxy)thiacalix[4]arene and 1,3-disubstituted bis(carbamoylmethoxy)thiacalix [4]arene, depending on the base used.

机译：四硫杂杯[4]芳烃与2-溴乙酰胺的直接O-烷基化反应得到四（氨基甲酰基甲氧基）硫杂杯[4]芳烃和1,3-二取代的双（氨基甲酰基甲氧基）硫杂杯[4]的两个构象异构体（圆锥和1,3-交替） ] arene，取决于所用的碱。

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《Journal of Chemical Research. Synopses》 |2009年第1期|共4页
作者
Rahman S; Shimizu T; Xi Z; Yamato T;
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正文语种 eng
中图分类化学;
关键词
thiacalix4arene; O-alkylation; template effect; conformation; intramolecular hydrogen bond; CALIXARENES; DERIVATIVES; RECEPTORS; IONS; COMPLEXATION; ACID; METACYCLOPHANES; INCLUSION;

机译：硫杂杯[4]芳烃;O-烷基化;模板效应;构象;分子内氢键;杯芳烃;衍生物;受体;离子;络合物;酸;巯基甲酚;

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1. Metal template effect on O-alkylation of tetrathiacalix[4]arene with 2-bromoacetamide to afford tetrakis(carbamoylmethoxy)thiacalix [4]arenes with cone and 1,3-alternate conformation [J] . Rahman S, Shimizu T, Xi Z, Journal of Chemical Research. Synopses . 2009,第1期

机译：金属模板对四硫杂杯[4]芳烃与2-溴乙酰胺的O-烷基化的影响，得到具有圆锥和1,3-交替构象的四（氨基甲酰基甲氧基）硫杂杯[4]芳烃
2. Hard-Soft Receptors,Tetrakis[(N,N-diethyIaminocarbonyl)methoxy] thiacalix[4]arene Derivatives with cone and 1,3-alternate Conformation [J] . CAROL PEREZ CASAS, TAKEHIKO YAMATO Journal of Inclusion Phenomena and Macrocyclic Chemistry . 2005,第1a2期

机译：硬质受体，具有圆锥和1,3-交替构型的四[[（N，N-二硫代氨基氨基羰基）甲氧基]硫杂杯[4]芳烃衍生物
3. p-tert-Butyl Thiacalix[4]arenes Functionalized with Amide and Hydrazide Groups at the Lower Rim in Cone, Partial Cone, and 1,3-Alternate Conformations Are "Smart" Building Blocks for Constructing Nanosized Structures with Metal Cations of s-, p-, and d-Elements in the Organic Phase [J] . Yushkova EA, Stoikov II Langmuir: The ACS Journal of Surfaces and Colloids . 2009,第9期

机译：对-叔丁基硫杂杯[4]芳烃在圆锥，部分圆锥和1,3-交替构型下边缘具有酰胺基和酰肼基官能团，是构建具有s-，金属阳离子的纳米级结构的“智能”构建基块。有机相中的p和d元素
4. Syntheses and Structures of Transition Metal Thiacalix4arene or Mercaptothiacalix4arene Complexes [C] . Toshiaki Suzuki, Kenii Hirata, Kohei Washizaki, Symposium on Organometallic Chemistry . 2003

机译：过渡金属的合成和结构ThiCalix 4芳烃或巯基噻吩（巯基）芳烃配合物
5. Thiacalix4arene: New protection for metal nanoclusters [O] . Zong-Jie Guan, Jiu-Lian Zeng, Zi-Ang Nan, 2016

机译：硫杂杯4芳烃：金属纳米簇的新保护
6. Synthesis of para- and meta-imino- or -amino-methyl pyridyl-appended p-tert-butyl-calix4arene or p-tert-butyl-thiacalix4arene in 1,3-alternate conformation [O] . M. H. Noamane, S. Ferlay, R. Abidi, 2017

机译：在1,3-交替构象中合成比酰基 - 甲基吡啶基 - 吡啶基吡啶基吡啶基P-叔丁基胶碱4芳烃4芳烃4芳烃

Metal template effect on O-alkylation of tetrathiacalix[4]arene with 2-bromoacetamide to afford tetrakis(carbamoylmethoxy)thiacalix [4]arenes with cone and 1,3-alternate conformation

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