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Diffusion in Quasi-One-Dimensional Periodic Structures

机译:准一维周期结构的扩散

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摘要

The problem of diffusion in quasi-one-dimensional structures (tubes and channels) of varying cross section can be formulated to study the transport of particles in zeolites, soils, and other porous materials, in membrane channels and nanotubes, and also in a number of other physicochemical and biological processes [1,2]. The interest in this problem is caused by the advances in creating new materials and the significant progress in experimental research. The variation of the shape of a tube along its axis affects the space accessible for diffusion. The thus induced dependence of the entropy of a particle on its position determines the physics of the problem: tube expansions act as entropy wells and tube constrictions do as entropy barriers.
机译:可以制定不同横截面的准一维结构(管和通道)中的扩散问题,以研究颗粒在沸石,土壤和其他多孔材料中,在膜通道和纳米管中以及在许多中的迁移其他理化和生物学过程[1,2]。人们对这个问题的兴趣是由新材料的开发和实验研究的重大进展引起的。管子沿其轴线的形状变化会影响可扩散的空间。因此,粒子的熵对其位置的依赖性决定了问题的物理性质:管膨胀充当熵井,管收缩充当熵屏障。

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