Conversion of {Fe(NO) _2} ~(10) dinitrosyl iron to nitrato iron(iii) species by molecular oxygen

Skodje K.M.; Williard P.G.; Kim E.

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Conversion of {Fe(NO) _2} ~(10) dinitrosyl iron to nitrato iron(iii) species by molecular oxygen

机译：{Fe（NO）_2}〜（10）二亚硝酰基铁通过分子氧转化为亚硝酸根铁（iii）物种

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A new {Fe(NO) _2} ~(10) dinitrosyl iron complex possessing a 2,9-dimethyl-1,10-phenanthroline ligand has been prepared. This complex exhibits dioxygenase activity, converting NO to nitrate (NO _3 ~-) anions. During the oxygenation reaction, formation of reactive nitrating species is implicated, as shown in the effective o-nitration with a phenolic substrate.

机译：制备了具有2,9-二甲基-1,10-菲咯啉配体的新的{Fe（NO）_2}〜（10）二亚硝基铁配合物。该络合物具有双加氧酶活性，可将NO转化为硝酸根（NO_3〜-）阴离子。在氧合反应期间，暗示了反应性硝化物质的形成，如与酚醛底物的有效邻硝化所示。

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《Dalton transactions: An international journal of inorganic chemistry 》 |2012年第26期| 共3页
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Skodje K.M.; Williard P.G.; Kim E.;
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1. Conversion of {Fe(NO) _2} ~(10) dinitrosyl iron to nitrato iron(iii) species by molecular oxygen [J] . Skodje K.M., Williard P.G., Kim E. Dalton transactions: An international journal of inorganic chemistry . 2012 ,第26期

机译：{Fe（NO）_2}〜（10）二亚硝酰基铁通过分子氧转化为亚硝酸根铁（iii）物种
2. NO-to-[N2O2](2-)-to-N2O Conversion Triggered by {Fe(NO)(2)}(10)-{Fe(NO)(2)}(9) Dinuclear Dinitrosyl Iron Complex [J] . Wu Wun-Yan, Hsu Chia-Ning, Hsieh Chieh-Hsin, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2019 ,第15期

机译：由{Fe（否）（2）}（10） - {Fe（2）（2）}（2）（2）（2）}（9）二核二硝基铁复合物触发的NO-[N2O2]（2 - ） - 至N2O转换
3. The Generation of Superoxide Radicals by Complex III in Heart Mitochondria and the Antioxidant Effect of Dinitrosyl Iron Complexes at Different Partial Pressures of Oxygen [J] . A. L. Dudylina, M. V. Ivanova, K. B. Shumaev, Biophysics . 2016 ,第2期

机译：不同氧分压下复合物III在心脏线粒体中产生超氧自由基和二亚硝基铁络合物的抗氧化作用
4. Sheet Polymeric Iron (III) Porphyrin Complexes Catalytic Oxidation of Styrene With Molecular Oxygen [C] . LI Xiaodong, WANG Xiaofeng, ZHU Yuancheng, International Conference on Frontiers of Manufacturing and Design Science . 2014

机译：薄层聚合物铁（III）卟啉复合物催化氧化苯乙烯与分子氧
5. Model complexes as probes of heme and nonheme enzymatic mechanisms: (1) Ferric peroxo porphyrin complexes as mimics of P450 enzymes using the ferric peroxo species as an active oxidant. (2) Strongly oxidizing iron (III) complexes as models of the active site intermediates of lipoxygenase. [D] . Wertz, Diana L. 1999

机译：将复合物建模为血红素和非血红素酶机制的探针：（1）使用过氧化铁物种作为活性氧化剂，将过氧化铁卟啉复合物模拟为P450酶。（2）强氧化铁（III）络合物作为脂氧合酶活性位点中间体的模型。
6. Phenol Nitration Induced by a {Fe(NO)2}10 Dinitrosyl Iron Complex [O] . Nhut Giuc Tran, Harris Kalyvas, Kelsey M. Skodje, -1

机译：酚硝化诱导由{的Fe（NO）2} 10 Dinitrosyl铁络合物
7. NO-to-N2O22-toN2O Conversion Triggered by {Fe(NO)2}10-{Fe(NO)2}9 Dinuclear Dinitrosyl Iron Complex [O] . -1

机译：由{fe（no）2}触发的{fe（no）2}触发的2-ton2o转换2} 9二核二硝基铁复合物
8. Organotransition-Metal Metallacarboranes. 19. Indenyliron(II) and -Iron(III)Complexes and Related Species. n6 Yields n5 Haptotropic Rearrangement, Electrochemistry, and Polyhedral Expansion of (Arene)Fe(Et2C2B4H4) Clusters [R] . Fessenbecker, A., Stephan, M., Grimes, R. N., 1991

机译：有机过渡 - 金属金属碳硼烷。 19.茚基铁（II）和 - 铁（III）配合物和相关物种。 n6产生n5的吸收重排，电化学和（芳烃）Fe（Et2C2B4H4）团簇的多面体膨胀

Conversion of {Fe(NO) _2} ~(10) dinitrosyl iron to nitrato iron(iii) species by molecular oxygen

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