Syntheses, Crystal Structures, and Luminescence Properties of Dinuclear Metal (Ag~+ and Cu~+) Complexes with the Ligand 2-MTPP [2-MTPP = 2-(Methylthio)-4-(pyridin-2-yl)pyrimidine]

摘要

Reactions of the ligand 2-MTPP [2-MTPP = 2-(methylthio)-4-(pyridin-2-yl)pyrimidine] with AgNO_3 and CuI produced dinuclear silver(I) (1) and copper(I) (2) complexes, respectively. Both complexes adopt a chair-like structure in which two 2-MTPP ligands and two metal ions are joined together through M-N and M-S coordination bonds. The luminescence properties of both complexes were investigated in solid state at room temperature.