A spectrophotometric, electron spin resonance, and calorimetric study of low-temperature postradiation living radical polymerization of vinyl monomers in the presence of C-60 fullerene

摘要

By means of UV-visible spectrophotometry, ESR spectroscopy, and calorimetry, it was shown that the low-temperature postradiation polymerization of vinyl monomers in the presence of C-60 fullerene (the yield of fullerene linking was above 90%) occurred via the radical mechanism in the living mode over the temperature range of 120-140 K.