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Comment on On the Nature of the Smectic A-to-Nematic Phase Transition of 8CB

机译:关于8CB的近晶相向向列相变性质的评论

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The paper by Oweimreen commented on hereafter describes density measurements of one of the most thoroughly investigated liquid crystalline compounds, 8CB. The main goal of the paper is to prove that a new "intermediate" phase exists between smectic A (SmA) and nematic (N), referred to as "more ordered nematic" or "less ordered smectic". The first-order character of the transition from smectic A to this intermediate phase is suggested. A detailed discussion of earlier results by other authors for 8CB and other compounds exhibiting the SmA-N phase transition is also presented. The author, however, does not cite or comment on the paper reporting the most precise molar volume measurements of the same phase transition for the same compound, 8CB, published in the same journal in 1999. The present comment provides a missing comparison between the results obtained by Oweimreen using a Paar densimeter and the dilatometric measurements by Zywocinski and Wieczorek.
机译:Oweimreen在随后发表的评论文章中描述了研究最深入的液晶化合物之一8CB的密度测量。本文的主要目的是证明在近晶A(SmA)和向列相(N)之间存在一个新的“中间”相,称为“更有序的向列相”或“低序的近晶相”。建议从近晶A过渡到该中间相的一阶特征。还介绍了其他作者对8CB和其他表现出SmA-N相变的化合物的早期结果的详细讨论。但是,作者没有引用或评论该论文,该论文报告了1999年在同一期刊上发表的同一化合物8CB的相同相变的最精确摩尔体积测量。该评论提供了结果之间缺少的比较由Oweimreen使用Paar密度计获得,Zywocinski和Wieczorek进行膨胀计测量。

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