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首页> 外文期刊>The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical >The Effect of Mutual Orientation on the Spectra of Metal Nanoparticle Rod-Rod and Rod-Sphere Pairs
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The Effect of Mutual Orientation on the Spectra of Metal Nanoparticle Rod-Rod and Rod-Sphere Pairs

机译:相互取向对金属纳米粒子棒-棒和棒-球对光谱的影响

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摘要

A simple quasistatic treatment for the plasmon resonance spectra of nanoparticle rod-rod and rod-sphere pairs is presented. Spectra are calculated for gold particle pairs at different distances and mutual orientations. For rod-rod and rod-sphere pairs, the spectral changes that occur as a result of interparticle interaction are different for end-to-end (axial) and side-to-side (lateral) orientations. Axial interactions generally lead to a red shift to the most intense (longitudinal axis) plasmon resonance band. Lateral interactions usually lead to a blue shift of the main plasmon band. In general, lateral orientation yields more pronounced spectral changes than the axial case, especially as the aspect ratio of the rod member(s) increases.
机译:提出了一种简单的准静态处理的纳米粒子棒-棒和棒-球对的等离激元共振谱。计算在不同距离和相互取向的金颗粒对的光谱。对于杆-杆和杆-球对,由于粒子间相互作用而发生的光谱变化对于端到端(轴向)和侧向(横向)方向是不同的。轴向相互作用通常导致红移到最强的(纵轴)等离子体共振带。横向相互作用通常导致主等离子体激元带发生蓝移。通常,横向取向比轴向情况产生更明显的光谱变化,尤其是当杆构件的纵横比增加时。

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