Cyclotransformation of Azinium Salts into Hydrogenated Cyclic Alkylamino Ketones

V. I. Terenin; A. S. Ivanov

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Cyclotransformation of Azinium Salts into Hydrogenated Cyclic Alkylamino Ketones

机译：zi盐环化转化为氢化环烷基氨基酮

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摘要

A study was carried out on the nucleophilic cyclotransformation of pyrrolo[1,2-a]pyrazinium salts and isoquinolinium salts containing a methyl group in the α-position. A method for the preparation of alkylaminotetrahydroindolizinones and tetralones was proposed.

机译：研究了在α位含有甲基的吡咯并[1,2-a]吡嗪鎓盐和异喹啉鎓盐的亲核环转化。提出了一种制备烷基氨基四氢吲哚并酮和四氢萘酮的方法。

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《Chemistry of heterocyclic compounds》 |2005年第10期|共7页
作者
V. I. Terenin; A. S. Ivanov;
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正文语种 eng
中图分类杂环化合物;
关键词
isoquinoline; pyrrolo1; 2-apyrazine; 5; 6; 7; 8-tetrahydroindolizinone; α-tetralone; nucleophilic rearrangement;

机译：异喹啉;吡咯并[1;2-a]吡嗪;5;6;7;8-四氢吲哚酮;α-四氢萘酮;亲核重排;

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专利

1. Cyclotransformation of Azinium Salts into Hydrogenated Cyclic Alkylamino Ketones [J] . V. I. Terenin, A. S. Ivanov Chemistry of heterocyclic compounds . 2005,第10期

机译：zi盐环化转化为氢化环烷基氨基酮
2. Synthesis of alpha-enaminones from cyclic ketones and anilines using oxoammonium salt as an oxygen transfer reagent [J] . Green chemistry . 2020,第6期

机译：使用氧铵盐作为氧转移试剂的环酮和苯胺的合成α-烯胺酮
3. Highly Enantioselective Synthesis of Fused Tri- and Tetrasubstituted Aziridines: aza-Darzens Reaction of Cyclic Imines with alpha-Halogenated Ketones Catalyzed by Bifunctional Phosphonium Salt [J] . Pan Jianke, Wu Jia-Hong, Zhang Hongkui, Angewandte Chemie . 2019,第22期

机译：融合的三唑和四氢的氮化含量高度致密的合成：通过双官能鏻盐催化的α-卤化酮的环状亚胺的Aza-Dirzens反应
4. Synthesis of potassium salts of 2,4-diamino(alkylamino)-6-dinitromethyl-1,3,5-triazine and 2-hydrazinyl-4-amino(alkylamino)-6-dinitromethyl-1,3,5-triazine [C] . Alexander A. Gidaspov, Vladimir V. Bakharev, Olga V. Golovina, Seminar on New Trends in Research of Energetic Materials . 2014

机译：2,4-二氨基（烷基氨基）-6-二硝基甲基-1,3,5-三嗪和2-肼基-4-氨基（烷基氨基）-6-二硝基甲基-1,3,5-三嗪的钾盐的合成
5. Regioselective, Asymmetric α,α-Bisalkylation of Ketones via N-Amino Cyclic Carbamate Chiral Auxiliaries: Methodology Development and Application to the Total Synthesis of both (+)- and (-)-Stigmolone and Apratoxin D [D] . Wengryniuk, Sarah Elizabeth 2012

机译：通过N-氨基环状氨基甲酸酯手性助剂的酮的区域选择性，不对称α，α-双烷基化：方法学的发展和在（+）-和（-）-Stigmolone和Apratoxin D的总合成中的应用
6. Direct β-Functionalization of Cyclic Ketones with Aryl Ketones via the Merger of Photoredox and Organocatalysis [O] . Filip R. Petronijević, Manuel Nappi, David W. C. MacMillan -1

机译：通过光氧化还原和有机催化的结合将环酮与芳基酮直接进行β-官能化
7. N-(pyridylmethyl)azinium salts: precursors of pyridyl-stabilized azinium N-ylides [O] . Agejas Chicharro, Francisco Javier, Cuadro Palacios, Ana María, Pastor Maeso, Manuel, 1995

机译：N-（吡啶基甲基）叠氮盐：吡啶基稳定的叠氮化N-基化物的前体

Cyclotransformation of Azinium Salts into Hydrogenated Cyclic Alkylamino Ketones

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