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Regioselective, Asymmetric α,α-Bisalkylation of Ketones via N-Amino Cyclic Carbamate Chiral Auxiliaries: Methodology Development and Application to the Total Synthesis of both (+)- and (-)-Stigmolone and Apratoxin D

机译：通过N-氨基环状氨基甲酸酯手性助剂的酮的区域选择性，不对称α，α-双烷基化：方法学的发展和在（+）-和（-）-Stigmolone和Apratoxin D的总合成中的应用

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作者
Wengryniuk, Sarah Elizabeth;
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作者单位

Duke University;

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授予单位 Duke University;
学科
学位 Ph.D.
年度 2012
页码 326 p.
总页数 326
原文格式 PDF
正文语种 eng
中图分类
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1. Regioselective Asymmetric a,a-Bisalkylation of Ketones via Complex-Induced Syn-Deprotonation of Chiral N-Amino Cyclic Carbamate Hydrazones [J] . Sarah E. Wengryniuk, Daniel Lim, Don M. Coltart Journal of the American Chemical Society . 2011,第22期

机译：经由区域性手性N-氨基环状氨基甲酸酯Hy的复合物诱导的反去质子化反应使酮的区域选择性不对称a，a-双烷基化
2. Simple and Efficient Asymmetric alpha-Alkylation and alpha,alpha-Bisalkylation of Acyclic Ketones by Using Chiral N-Amino Cyclic Carbamate Hydrazones [J] . Daniel him, Don M.Coltart Angewandte Chemie . 2008,第28期

机译：通过使用手性N-氨基环状氨基甲酸酯Hy，简单有效的无环酮的不对称α-烷基化和α，α-双烷基化
3. A formal asymmetric synthesis of apratoxin D via advanced-stage asymmetric ACC alpha,alpha-bisalkylation of a chiral nonracemic ketone [J] . Dey Sumit, Wengryniuk Sarah E., Tarsis Emily M., Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2015,第22期

机译：通过手性非外消旋酮的高级不对称ACCα，α-双烷基化进行Apratoxin D的形式不对称合成
4. Total Synthesis, Biological Evaluation, and Binding Protein Network Analysis of Natural Product Cyclic Depsipeptides, Spiruchostatin A and Apratoxin A [C] . Takayuki Doi, Yoshitaka Numajiri, Yusuke Iijima Japanese peptide symposium . 2011

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机译：有机硼烷的手性合成。 22.选择性削减。 44.异丙基氨基烷基氯硼烷中烷基取代基的空间要求对代表性酮的不对称还原的影响

Regioselective, Asymmetric α,α-Bisalkylation of Ketones via N-Amino Cyclic Carbamate Chiral Auxiliaries: Methodology Development and Application to the Total Synthesis of both (+)- and (-)-Stigmolone and Apratoxin D

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