Investigation of the Effect of the NH…OC Hydrogen Bond from Cys69 to PYP Chromophore Using Novel Active-center Model Compound

Kentaro Okamoto; Norio Hamada; Toshiaki Sumi

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Investigation of the Effect of the NH…OC Hydrogen Bond from Cys69 to PYP Chromophore Using Novel Active-center Model Compound

机译：用新型活性中心模型化合物研究Cys69的NH…OC氢键对PYP发色团的影响

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A PYP active-center model compound containing a hydrogen bond to the conjugated carbonyl oxygen was synthesized and its effect on the electronic properties of the chromophore were investigated. The intramolecular hydrogen bond induces significant change in the absorption maximum of the π-π* transition in the chromophore.

机译：合成了一个具有与共轭羰基氧键合氢键的PYP活性中心模型化合物，并研究了其对生色团电子性质的影响。分子内氢键在生色团中引起最大的π-π*跃迁吸收变化。

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《Chemistry Letters》 |2009年第5期|共2页
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Kentaro Okamoto; Norio Hamada; Toshiaki Sumi;
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正文语种 eng
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1. Investigation of the Effect of the NH…OC Hydrogen Bond from Cys69 to PYP Chromophore Using Novel Active-center Model Compound [J] . Kentaro Okamoto, Norio Hamada, Toshiaki Sumi Chemistry Letters . 2009,第5期

机译：用新型活性中心模型化合物研究Cys69的NH…OC氢键对PYP发色团的影响
2. Energetics of the O-H Bond and of Intramolecular Hydrogen Bonding in HOC6H4C(O)Y(Y=H,CH3,CH2CH=CH2,C ident to CH,CH2F,NH2,NHCH3,N02,OH,OCH3,OCN,CN,F,Cl,SH,and SCH3)Compounds [J] . Carlos E.S.Bernardes, Manuel E.Minas da Piedade The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2008,第40期

机译：HOC6H4C（O）Y（Y = H，CH3，CH2CH = CH2，C与CH，CH2F，NH2，NHCH3，NO2，OH，OCH3，OCN，CN，F，C相同的OH键和分子内氢键的能量Cl，SH和SCH3）化合物
3. Systematic Investigation of Relationship between Strength of NH···S Hydrogen Bond and Reactivity of Molybdoenzyme Models [J] . Taka-aki Okamura, Yasuhito Ushijima, Yui Omi, Inorganic Chemistry . 2013,第1期

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5. A hydrogen bonding ortho-directing effect for the iridium catalyzed borylation of NH(t-BOC) aromatics. [D] . Roosen, Philipp C. 2011

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Investigation of the Effect of the NH…OC Hydrogen Bond from Cys69 to PYP Chromophore Using Novel Active-center Model Compound

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