An easy route to optically active 1-substituted-1-pyridyl-methylamines by diastereoselective reduction of enantiopure N-tert-butanesulfinyl ketimines

Chelucci G; Baldino S; Chessa S; Pinna GA; Soccolini F

首页> 外文期刊>Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry >An easy route to optically active 1-substituted-1-pyridyl-methylamines by diastereoselective reduction of enantiopure N-tert-butanesulfinyl ketimines

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An easy route to optically active 1-substituted-1-pyridyl-methylamines by diastereoselective reduction of enantiopure N-tert-butanesulfinyl ketimines

机译：通过非对映纯还原对映体纯的N-叔丁烷亚磺酰基酮亚胺制得旋光的1-取代的1-吡啶基-甲基胺的简便方法

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The reduction of enantiopure N-tert-butanesulfinyl ketimines derived from pyridyl ketones afforded the related N-tert-but-anesulfinyl amines with high yields and diastereoselectivities. (c) 2006 Elsevier Ltd. All rights reserved.

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《Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry》 |2006年第22期|共7页
作者
Chelucci G; Baldino S; Chessa S; Pinna GA; Soccolini F;
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正文语种 eng
中图分类有机化学;
关键词
NICOTINIC ACETYLCHOLINE-RECEPTORS; P-TOLUENESULFINYL KETIMINES; ASYMMETRIC-SYNTHESIS; ENANTIOSELECTIVE CATALYSIS; TRANSFER HYDROGENATION; CHIRAL LIGANDS; COMPLEXES; KETONES; (S)-1-(2-PYRIDYL)ALKYLAMINES; DIETHYLZINC;

机译：烟碱型乙酰胆碱受体;对甲苯磺酰基酮亚胺;不对称合成;对映选择性催化;转移加氢;手性配体;化合物;酮;（S）-1-（2-吡啶基）烷基;二乙炔;

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1. An easy route to optically active 1-substituted-1-pyridyl-methylamines by diastereoselective reduction of enantiopure N-tert-butanesulfinyl ketimines [J] . Chelucci G, Baldino S, Chessa S, Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry . 2006,第22期

机译：通过非对映纯还原对映体纯的N-叔丁烷亚磺酰基酮亚胺制得旋光的1-取代的1-吡啶基-甲基胺的简便方法
2. Highly Diastereoselective and Enantioselective Synthesis of Enantiopure C_2-Symmetrical Vicinal Diamines by Reductive Homocoupling of Chiral N-tert-Butanesulfinyl lmines [J] . Yu-Wu Zhong, Kenji Izumi, Ming-Hua Xu, Organic letters . 2004,第25期

机译：手性N-叔丁烷亚磺酰基亚胺的还原均相偶联对映体纯C_2-对称邻二胺的非对映选择性和对映选择性。
3. Diastereoselective reduction of enantiopure N-p-toluenesulfinyl ketimines derived from pyridyl ketones [J] . Chelucci G, Baldino S, Chessa S Tetrahedron . 2006,第4期

机译：非对映选择性还原衍生自吡啶基酮的对映体纯N-对甲苯亚磺酰基酮亚胺
4. Router power reduction by active performance control realized with support vector machines [C] . Kawase Hiroshi, Hasegawa Hiroshi, Sato Ken-ichi International Conference on Computing, Networking and Communications . 2015

机译：通过使用支持向量机的主动性能控制来降低路由器功耗
5. Diastereoselective palladium-catalyzed formate reduction of allylic carbonates as a route to polypropionate systems. [D] . Chau, Anh. 2004

机译：非对映选择性钯催化的甲酸烯丙基碳酸盐的甲酸还原，这是通向聚丙烯酸酯体系的一种途径。
6. Diastereoselective Diels–Alder Reactions of N-Sulfonyl-1-aza-13-butadienes With Optically Active Enol Ethers: An Asymmetric Variant of the 1-Azadiene Diels–Alder Reaction [O] . Ryan C. Clark, Steven S. Pfeiffer, Dale L. Boger -1

机译：N-磺酰基-1-氮杂-13-丁二烯与光学活性烯醇醚的非对映选择性Diels-Alder反应：1-Azadiene Diels-Alder反应的不对称变化
7. Highly Diastereoselective and Enantioselective Synthesis of Enantiopure C2-Symmetrical Vicinal Diamines by Reductive Homocoupling of Chiral N-tert-Butanesulfinyl Imines [O] . -1

机译：通过Chiral N-Tert-Butanesulfinyl亚胺的还原同耦合对对抗C2-对称的邻亚胺的高度映射性和对映选择性的合成

An easy route to optically active 1-substituted-1-pyridyl-methylamines by diastereoselective reduction of enantiopure N-tert-butanesulfinyl ketimines

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