Stereoselective preparation of pyrrolidin-2-ones from a Z-enoate derived from D-(+)-mannitol

Domingos JLO; Lima EC; Dias AG; Costa PRR

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Stereoselective preparation of pyrrolidin-2-ones from a Z-enoate derived from D-(+)-mannitol

机译：从D-（+）-甘露醇衍生的Z-烯酸酯立体选择性地制备吡咯烷二酮

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Chiral pyrrolidin-2-ones have been prepared through the reductive cyclisation of gamma-nitro-esters. These intermediates were obtained by syn-stereoselective conjugate addition of nitronates to a Z-enoate derived from D-(+)-mannitol. This route was used to prepare the cognitive enhancer (S)-WEB-1868. (C) 2004 Elsevier Ltd. All rights reserved.

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《Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry》 |2004年第15期|共2页
作者
Domingos JLO; Lima EC; Dias AG; Costa PRR;
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正文语种 eng
中图分类有机化学;
关键词
MICHAEL ADDITION; ACID; NITROMETHANE; ACETONIDE;

机译：迈克尔加成;酸;亚硝基乙烷;乙酰;

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1. Stereoselective preparation of pyrrolidin-2-ones from a Z-enoate derived from D-(+)-mannitol [J] . Domingos JLO, Lima EC, Dias AG, Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry . 2004,第15期

机译：从D-（+）-甘露醇衍生的Z-烯酸酯立体选择性地制备吡咯烷二酮
2. Stereoselective Synthesis of beta-Lactams by Using D-Mannitol-Derived Oxazolidin-2-one as a Chiral Auxiliary [J] . Dong Gyun Shin, Hye Jin Heo, Jong-Gab Jun Synthetic Communications . 2005,第6期

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Stereoselective preparation of pyrrolidin-2-ones from a Z-enoate derived from D-(+)-mannitol

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