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Combustion Synthesis and Catalytic Activity of LaCoO3 for HMX Thermal Decomposition

机译:LaCoO3的燃烧合成及其对HMX热分解的催化活性

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摘要

Perovskite-type LaCoO3 was prepared by stearic acid solution combustion method and characterized by XRD, DSC-TG, and XPS techniques. The catalytic activities of LaCoO3 for HMX (octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine) thermal decomposition were investigated. The as-prepared LaCoO3 shows higher activity than the calcined one. This could be due to higher concentration of surface-adsorbed oxygen and hydroxyl species as well as higher BET surface area of the as-prepared LaCoO3.
机译:采用硬脂酸溶液燃烧法制备钙钛矿型LaCoO3,并通过XRD,DSC-TG和XPS技术对其进行表征。研究了LaCoO3对HMX(八氢-1,3,5,7-四硝基-1,3,5,7-四唑啉)热分解的催化活性。所制备的LaCoO3的活性比煅烧过的LaCoO3高。这可能是由于所制备的LaCoO3的表面吸附的氧和羟基物种浓度较高以及BET表面积较高。

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