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Amphiphilic block copolymers of PtBA-b-PMMA as compatibilizers for blends of PET and PMMA

机译:PtBA-b-PMMA的两亲嵌段共聚物,可作为相容剂用于PET和PMMA的共混物

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摘要

PET and PMMA were blended at various weight fractions. These blends were compatibilized by employing amphiphilic block copolymers of PtBA-b-PMMA, having three compositions (1:3, 1:1, 3:1) and three weight fractions (3, 5, and 7 wt%) using a co-rotating twin screw extruder. The blends were evaluated for their mechanical, Theological, and morphological properties. Overall, the compatiblized blends showed improvement in properties compared with the properties of noncompatiblized blends. Mechanical properties of the compatibilized blends improved with an increase in the PMMA and compatibilizer weight fractions. It was observed that the compatibilizer with lower molecular weight and lower glass transition temperature, typically at 5 wt%, provided the overall best properties.
机译:将PET和PMMA以各种重量分数混合。这些共混物通过使用具有三种组成(1:3、1:1、3:1)和三种重量分数(3、5和7 wt%)的PtBA-b-PMMA的两亲嵌段共聚物来增容旋转双螺杆挤出机。评价了共混物的机械,神学和形态学性能。总体而言,与非相容性共混物的性能相比,相容性共混物的性能有所改善。随着PMMA和增容剂重量分数的增加,增容共混物的机械性能得到改善。观察到具有较低分子量和较低玻璃化转变温度,通常为5重量%的增容剂提供了总体上最佳的性能。

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