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Development of UHMWPE Modified PP/PET Blends and Their Mechanical and Abrasive Wear Behavior

机译:UHMWPE改性PP / PET共混物的开发及其机械和磨料磨损行为

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In this study,polypropylene and polyethylene terephtha-late blend were modified by incorporating different percentages of ultrahigh molecular weight polyethylene(UHMWPE)ranging from 1 to 5 phr.Modified blends were prepared by melt mixing the PP/PET blend and UHMWPE.Ultimate tensile strength of UHMWPE filled blend was determined at 10,20,50,and 100 mm/min cross head speeds of testing.It was found that increase of cross head speed from 10 to 100 mm/min increases the tensile strength of PP/PET/UHMWPE blends.Maximum ultimate tensile strength is exhibited by the blend containing 2 phr UHMWPE.Breaking strain of the UHMWPE modified and unmodified PP/PET blend increased with the increase of cross head speed due to the highly entangled chain structure of UHMWPE.Shore A hardness of the filled blends also increased from 341 to 356,which is highest for 2 phr UHMWPE.High stress abrasive wear of UHMWPE modified blend was determined by using Suga abrasion tester,model NUS-1 Japan.Wear rate of the PP/PET(90/10)blends having 1,2,and 5 phr of UHMWPE was determined at different loads such as 1,3,5,and 7 N and sliding distances from 6.4 m to 25.6 m.Wear rate values show that UHMWPE has prominent effect on abrasive wear of PP/PET blends.Addition of 2 and 5 phr UHMWPE improved the wear resistance of PP/PET blends at different loads,which has been explained on the basis of improved bonding as compared with pure PP/PET blend and increased hardness.Maximum abrasive wear rate reduction was achieved by adding 2 phr UHMWPE in PP/PET(90/10)blend.
机译:在这项研究中,聚丙烯和聚对苯二甲酸乙二醇酯共混物通过掺入1至5 phr的不同百分比的超高分子量聚乙烯(UHMWPE)进行改性。通过将PP / PET共混物和UHMWPE熔融混合制备改性共混物。在10、20、50和100 mm / min的十字头测试速度下确定UHMWPE填充共混物的含量。发现十字头速度从10 mm / min增加到100 mm / min会增加PP / PET / UHMWPE的拉伸强度含2 phr UHMWPE的共混物表现出最大的极限拉伸强度.UHMWPE改性和未改性PP / PET混合物的断裂应变由于UHMWPE的高度缠结的链结构而随着十字头速度的增加而增加。填充的混合物也从341增加到356,这是2 phr UHMWPE的最高值。使用日本NUS-1型Suga磨损测试仪确定了UHMWPE改性混合物的高应力磨料磨损。PP /在1,3,5,7 N等不同载荷下以及6.4 m至25.6 m的滑动距离下确定了具有1,2和5 phr UHMWPE的PET(90/10)混合物。磨损率值表明UHMWPE具有对PP / PET混合物的磨料磨损具有显着影响。添加2和5 phr UHMWPE可以改善PP / PET混合物在不同负载下的耐磨性,这是基于与纯PP / PET混合物相比粘结性得到了改善的原因而解释的通过在PP / PET(90/10)共混物中添加2 phr UHMWPE可最大程度地降低磨料磨损率。

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