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Structural, morphological characteristics and optical properties of Y doped ZnO thin films by sol-gel spin coating method

机译:溶胶-凝胶旋涂法掺杂Y的ZnO薄膜的结构,形貌特征和光学性质

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Un-doped and Y doped ZnO thin films were deposited successfully by sol-gel spin coating method with different Y concentrations. The X-ray diffraction spectra revealed that all the films have poly-crystalline of hexagonal wurtzite structure. SEM images of the films show different micro structure with nano clusters and show a reduction in surface roughness. The EDX spectrum confirms the presence of Zn, O and Y elements in the prepared films. The optical transmittance spectrum indicates the average transmittance of the films is increased from 78% to 83%. The optical band gaps of the ZnO films were changed from 3.33 eV to 3.43 eV with increasing Y doping. PL spectra show the blue shift in near band edge (NBE) UV emission. The presence of functional groups and the chemical bonding is confirmed by FTIR spectra. The Hall measurements show that the films have n-type conductivity.
机译:采用溶胶-凝胶旋涂法成功沉积了不同掺杂浓度的未掺杂和掺Y的ZnO薄膜。 X射线衍射光谱表明,所有膜均具有六方纤锌矿结构的多晶体。薄膜的SEM图像显示具有纳米簇的不同微观结构,并且表面粗糙度降低。 EDX光谱证实了所制备的膜中存在Zn,O和Y元素。光学透射光谱表明膜的平均透射率从78%增加到83%。随着Y掺杂的增加,ZnO薄膜的光学带隙从3.33 eV变为3.43 eV。 PL光谱显示近带边缘(NBE)UV发射中的蓝移。 FTIR光谱证实了官能团和化学键的存在。霍尔测量表明该膜具有n型导电性。

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