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Solvent Vapour Use - The Unintended Consequences in Textile Conservation

机译:溶剂蒸汽使用 - 纺织保护中的意外后果

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The impact of solvent vapour from two solvents, acetone and industrial denatured alcohol (IDA), commonly used in adhesive reactivation in textile conservation, when applied to artificially soiled silk fabric through either Gore-Tex (R) or Reemay (R) membranes for exposure times of either 1 or 3 min, was measured using microscopy and ImageJ to monitor the movement of the solid particulates of the soiling, and Fourier transform infrared spectroscopy with attenuated total reflectance (FTIR-ATR) to monitor the movement of the oily components. Analysis using these techniques successfully showed the movement of large particulates through the textile and a decrease in the presence of oil. Analysis with FTIR-ATR showed that the application of solvent vapour by a poultice method produces more than just a surface change and the vapour can penetrate far enough into the fibres to cause a change in the level of oil through the entire textile. The results showed that the solvents and barrier membranes have characteristic differences which impact on the changes on the soiling. The application of acetone produced a greater change in the movement of oil on the front and back of the samples than the application of IDA, while a comparison between the barrier membranes showed a greater change occurring in the level of oil with the use of Gore-Tex (R) rather than Reemay (R). The time of exposure to solvent vapour made little difference to the changes to the textile soiling. Quantitatively significant results were gathered from analysis of the changes in the oil measured with FTIR-ATR, and qualitative changes in the large particulate soiling, demonstrating the potential usefulness of ImageJ open access software in future historic textile soiling monitoring studies.
机译:溶剂蒸汽从两种溶剂,丙酮和工业变性醇(IDA)的影响,通常用于纺织品保守中的粘合再活化,当通过Gore-Tex或Reemay膜施用于人工污染的丝绸织物时施用于纺织织物1或3分钟的时间使用显微镜和ImageJ测量,以监测污染的固体颗粒的运动,以及傅里叶变换红外光谱与减毒的总反射率(FTIR-ATR)来监测油性组分的运动。使用这些技术的分析成功地显示了大颗粒通过纺织品的运动和油的降低。使用FTIR-ATR的分析表明,溶剂蒸汽通过泥浆方法的应用产生的不仅仅是表面变化,蒸气可以足够远进入纤维中,以引起整个纺织品的油水平的变化。结果表明,溶剂和屏障膜具有对污染变化影响的特征差异。丙酮的应用在样品的前后的油状物上产生了更大的变化,而不是IDA的应用,而阻隔膜之间的比较显示出在油的水平中发生更大的变化,使用血液 - tex(r)而不是重新安置(r)。暴露于溶剂蒸汽的时间对纺织品污染的变化产生了几乎没有差异。定量显着的结果从分析了用FTIR-ATR测量的油的变化分析,并且大颗粒污染的定性变化,展示了ImageJ开放式软件在未来的历史造成污染监测研究中的潜在有用性。

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