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Solvent Vapour Use - The Unintended Consequences in Textile Conservation

机译:溶剂蒸气的使用-纺织品保护中的意外后果

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The impact of solvent vapour from two solvents, acetone and industrial denatured alcohol (IDA), commonly used in adhesive reactivation in textile conservation, when applied to artificially soiled silk fabric through either Gore-Tex (R) or Reemay (R) membranes for exposure times of either 1 or 3 min, was measured using microscopy and ImageJ to monitor the movement of the solid particulates of the soiling, and Fourier transform infrared spectroscopy with attenuated total reflectance (FTIR-ATR) to monitor the movement of the oily components. Analysis using these techniques successfully showed the movement of large particulates through the textile and a decrease in the presence of oil. Analysis with FTIR-ATR showed that the application of solvent vapour by a poultice method produces more than just a surface change and the vapour can penetrate far enough into the fibres to cause a change in the level of oil through the entire textile. The results showed that the solvents and barrier membranes have characteristic differences which impact on the changes on the soiling. The application of acetone produced a greater change in the movement of oil on the front and back of the samples than the application of IDA, while a comparison between the barrier membranes showed a greater change occurring in the level of oil with the use of Gore-Tex (R) rather than Reemay (R). The time of exposure to solvent vapour made little difference to the changes to the textile soiling. Quantitatively significant results were gathered from analysis of the changes in the oil measured with FTIR-ATR, and qualitative changes in the large particulate soiling, demonstrating the potential usefulness of ImageJ open access software in future historic textile soiling monitoring studies.
机译:通过Gore-Tex(R)或Reemay(R)膜施加到人工污染的真丝织物上时,两种溶剂(丙酮和工业变性醇(IDA))中溶剂蒸汽的影响通常用于纺织品保护中的胶粘剂再生中。使用显微镜和ImageJ测量1分钟或3分钟的时间,以监测污染的固体颗粒的运动,并使用具有衰减的全反射率(FTIR-ATR)的傅里叶变换红外光谱法监测油性组分的运动。使用这些技术的分析成功地表明了大颗粒在纺织品中的运动,并且减少了油的存在。 FTIR-ATR的分析表明,通过膏剂法施加的溶剂蒸气不仅会产生表面变化,而且蒸气会渗入纤维中足够远的距离,从而导致整个纺织品的油含量发生变化。结果表明,溶剂和阻隔膜的特性差异会影响污物的变化。与使用IDA相比,使用丙酮在样品前部和后部产生的油的运动变化更大,而在阻隔膜之间进行的比较显示,使用Gore- Tex(R)而不是Reemay(R)。暴露于溶剂蒸汽中的时间对织物污染的变化影响很小。通过分析使用FTIR-ATR测量的机油变化以及大颗粒污物的质变,收集到了数量显着的结果,这表明ImageJ开放访问软件在未来的历史性纺织品污物监测研究中具有潜在的实用性。

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