Biochar-amendment-reduced cotransport of graphene oxide nanoparticles and dimethyl phthalate in saturated porous media

摘要

Production and application of graphene oxide (GO) and biochar for water and soil treatment is steadily growing, driving the necessity to understand the cotransport behavior of contaminants and GO nanopar-ticles in porous media and the possible effect of biochar to reduce their cotransport. The cotransport of GO nanoparticles and dimethyl phthalate (DMP) as a model in a sand column and biochar-amended sand column (biochar column) was compared. The transport of DMP in the test columns was independent of the solution ionic strength (IS), while the transport of GO decreased with increased IS due to the enhanced aggregation of GO nanoparticles. The sand column had no retention capacity (less than 1%) for DMP, while the biochar column had significantly increased retention of DMP (100%). The retention of GO in the biochar column was significantly higher than that of the sand column because biochar can improve the roughness of the media and adsorb GO via π-π interactions. Under low-IS conditions, GO facilitated DMP transport by providing vehicles and adsorption sites (vehicle effect). Due to reversible adsorption-desorption, the adsorbed DMP on GO could be released, resulting in tailing during the flushing phase. The vehicle effect of GO on DMP transport was significantly weakened in the biochar columns, and DMP tailing during the flushing phase was not observed in the biochar columns, which was attributed to the strong retention/adsorption of the biochar columns for both GO and DMP, higher affinity of DMP on biochar than GO, and desorption hysteresis of DMP on biochar. These observations are important for evaluating the potential role of biochar in soil and water remediation, as well as mitigating the health risks of GO and organic contaminants in the environment.