A comprehensive study on the leaching of metals from heated tobacco sticks and cigarettes in water and natural waters

摘要

The leaching behavior of Al, Cr, Ni, Cu, Zn, As, Se, Cd, Ba, Hg and Pb in water from two types of heat-not-burn tobacco sticks is presented here, and compared to that from conventional cigarettes. The total concentration of each metal in solid tobacco products was initially determined. Concentrations in used and unused tobacco sticks were similar and generally, lower than those in unused conventional cigarettes. Studies on the contribution of paper, filter and tobacco revealed that tobacco was the major source of metal contamination. Smoking conventional cigarettes reduced the total metal concentrations since a substantial amount of metals was retained in the ash; a post-consumption waste that is difficult to collect. Batch leaching tests were performed to determine dissolved concentrations as a function of time. With the exceptions of As and (in most cases) Hg that were not detected, metals were released at varying rates. At 24 h of soaking the percentage of metals leached ranged from 0.2-43%. The contribution of paper, filter and tobacco to the dissolved concentrations at 24 h of leaching was investigated and in almost all cases tobacco was the major source of metal contamination. The dissolved concentrations from ash were low as metals were strongly bound. Varying the pH, ionic strength and humic acids content at environmentally relevant values did not affect leaching of metals at 24 h of soaking. The use of river water, rain water and seawater as leachants was also not found to alter dissolved concentrations at 24 h compared to ultrapure water. The results presented here suggest that the consequences of improper disposal of tobacco products in the environment are two-sided and that next to the generation of plastic litter, discarded tobacco products can also act as point sources of metal contamination. Public education campaigns focusing on the environmental impact and best disposal practices are urgently needed.