In situ high-pressure synchrotron X-ray diffraction study of the structural stability in NdVO_4 and LaVO_4

摘要

Room-temperature angle-dispersive X-ray diffraction measurements on zircon-type NdVO_4 and monazite-type LaVO_4 were performed in a diamond-anvil cell up to 12 GPa. In NdVO_4, we found evidence for a non-reversible pressure-induced structural phase transition from zircon to a monazite-type structure at 6.5 GPa. Monazite-type LaVO_4 also exhibits a phase transition but at 8.6 CPa. In this case the transition is reversible and isomorphic. In both compounds the pressure induced transitions involve a large volume collapse. Finally, the equations of state and axial compressibilities for the low-pressure phases are also determined.