Preparation of allyl sulfoxides by palladium-catalyzed allylic alkylation of sulfenate anions

Maitro G; Prestat G; Madec D; Poli G

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Preparation of allyl sulfoxides by palladium-catalyzed allylic alkylation of sulfenate anions

机译：钯催化亚磺酸根阴离子的烯丙基烷基化制备烯丙基亚砜

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Palladium-catalyzed allylic alkylation of sulfenate anions, generated from beta-sulfinylesters by retro-Michael reaction, can take place under biphasic conditions. This new reaction provides a simple, mild, and efficient route to allyl sulfoxides in good yields.

机译：由β-亚磺酰基酯通过逆迈克尔反应产生的钯催化的亚磺酸根阴离子的烯丙基烷基化可以在两相条件下进行。该新反应为获得烯丙基亚砜提供了简单，温和，有效的途径，并且收率很高。

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来源
《The Journal of Organic Chemistry》 |2006年第19期|p. 7449-7454|共6页
作者
Maitro G; Prestat G; Madec D; Poli G;
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作者单位

Univ Paris 06, Inst Chim Mol, Chim Organ Lab, CNRS,UMR 7611,FR 2769, F-75252 Paris 05, France;

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
原文格式 PDF
正文语种 eng
中图分类有机化学;
关键词
PHASE-TRANSFER CATALYSIS; PARA-TOLYL SULFONES; ENANTIOENRICHED SULFOXIDES; STEREOSELECTIVE-SYNTHESIS; 1-ALKYNYL SULFOXIDES; OXIDATION; SULFINYLZINCATION; THIOLS; SALTS; INDUCTION;

机译：相转移催化;对甲苯磺酸;富含对映体的硫化物;立体选择性合成;1-炔基硫化物;氧化;磺化反应;硫醇;盐;诱导;
入库时间 2022-08-18 00:02:54

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Preparation of allyl sulfoxides by palladium-catalyzed allylic alkylation of sulfenate anions

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