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Room temperature ferromagnetism and optical properties of Cu~(2+)doped ZnO nanopowder by ultrasound assisted solid state reaction technique

机译:超声辅助固态反应技术研究Cu〜(2+)掺杂ZnO纳米粉的室温铁磁性和光学性质

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摘要

Cu~(2+) doped ZnO nanopowder was synthesized with the assistance of sonochemical method. Powder X-ray diffraction data confirms the prepared powder exhibit hexagonal wurtzite structure. From optical and EPR studies the Cu~(2+) ion occupied in tetragonally distorted octahedral site symmetry. The photo-luminescence (PL) spectrum at room temperature shows a strong ultraviolet emission (~378) and a strong, dominated defect related deep level emission (~435) in visible regions. Vibrational bands related to metal oxide bonding are evident form FT-IR studies. The magnetic measurement of the prepared sample shows good ferromagnetic property at room temperature.
机译:声化学法合成了Cu〜(2+)掺杂的ZnO纳米粉。粉末X射线衍射数据证实所制备的粉末显示出六方纤锌矿结构。从光学和EPR研究中,Cu〜(2+)离子以四边形扭曲的八面体位点对称性占据。室温下的光致发光(PL)光谱在可见光区域显示出强紫外线发射(〜378)和与缺陷有关的深能级强发射(〜435)。 FT-IR研究表明与金属氧化物键合有关的振动带很明显。所制备样品的磁性测量在室温下显示出良好的铁磁性能。

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