首页> 外文期刊>Journal of inorganic and organometallic polymers and materials >Transport Properties of La_(0.8)Sr_(0.2)Mn_3 and Bi_(0.95)Dy_(0.05)FeO_3 Based (0.5) La_(0.8)Sr_(0.2)MnO_3 + (0.5) Bi_(0.95)by_(0.05)FeO_3 Composite
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Transport Properties of La_(0.8)Sr_(0.2)Mn_3 and Bi_(0.95)Dy_(0.05)FeO_3 Based (0.5) La_(0.8)Sr_(0.2)MnO_3 + (0.5) Bi_(0.95)by_(0.05)FeO_3 Composite

机译:La_(0.8)Sr_(0.2)Mn_3和Bi_(0.95)Dy_(0.05)FeO_3基(0.5)La_(0.8)Sr_(0.2)MnO_3 +(0.5)Bi_(0.95)by_(0.05)FeO_3复合材料的输运性质

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Here, we report the structural and low temperature electrical properties of La0.8Sr0.2MnO3 (LSMO), Bi0.95Dy0.05FeO3 (BDFO) and their composite (0.5) LSMO + (0.5) BDFO prepared via solid-state reaction route. X-ray diffraction (XRD) data studies infers that both the compounds LSMO and BDFO are single phased in nature. Further XRD data analysis reveal that both these compounds display their presence in the composite sample. Both the parent samples of the composite were observed to have crystallized in rhombohedral (R3c) structure. The lattice structure was further verified via Raman Spectroscopic measurement technique. Low temperature transport properties study establishes the semiconducting nature of the composite. The dc resistivity data of ferromagnetic mettalic LSMO compound suggests that the electron-electron scattering is predominant in the metallic region whereas the semiconducting region in the composite sample [(0.5) LSMO + (0.5) BDFO] is well described using small polaron hopping and Mott's variable range hopping (VRH) models. Activation energy E-p was found to decrease with increase in magnetic field from 0 to 8T attributed to the decrease in the values of charge localization. The density of states Increases with magnetic field attributed to the suppression of magnetic domain scattering explained via Mott's VRH mechanism. High MR% is observed in both the LSMO sample and the composite one which increases with decrease in temperature.
机译:在这里,我们报告通过固态反应路线制备的La0.8Sr0.2MnO3(LSMO),Bi0.95Dy0.05FeO3(BDFO)及其复合材料(0.5)LSMO +(0.5)BDFO的结构和低温电性能。 X射线衍射(XRD)数据研究表明,化合物LSMO和BDFO均为自然相。进一步的XRD数据分析表明,这两种化合物均在复合样品中显示出它们的存在。观察到复合材料的两个母体样品均以菱形(R3c)结构结晶。通过拉曼光谱测量技术进一步验证了晶格结构。低温传输特性研究确定了复合材料的半导体性质。铁磁金属LSMO化合物的直流电阻率数据表明,电子-电子散射主要存在于金属区域,而复合样品[(0.5)LSMO +(0.5)BDFO]中的半导体区域使用小极化子跳变和Mott's很好地描述了可变范围跳变(VRH)模型。发现活化能E-p随着磁场从0增加到8T而降低,这归因于电荷定位值的降低。态密度随着磁场的增加而增加,这归因于通过Mott的VRH机制解释的磁畴散射的抑制。在LSMO样品和复合材料中均观察到较高的MR%,其随温度降低而增加。

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