The Effects of Solid-State Aging on the Intermetallic Compounds of Sn-Ag-Bi-In Solders on Cu Substrates

摘要

The growth behavior of the intermetallic compounds that formed at the interfaces between Sn-Ag-Bi-In solders and Cu substrates during solid-state aging is investigated. The compositions of the intermetallic compounds are Cu₃(Sn,In) near the Cu substrates and Cu₆(Sn,In)₅ near the solders; very little Bi or Ag was dissolved in the compounds. The aging temperatures were 120°C, 150°C, and 180°C for 5 days, 10 days, 20 days, and 40 days. The change in the morphology of Cu₆(Sn,In)₅ from scallop type to layer type was prominent at the aging temperature of 180°C. The thickness of the compound layers did not vary much at the lower aging temperatures but followed the diffusion- controlled mechanism at 180°C. Massive Kirkendall voids were observed in Cu₃(Sn,In) layers at the aging temperature of 180°C.