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Modeling The Electrical Impedance Response Of Ionic Polymer Transducers

机译:离子聚合物传感器的电阻抗响应建模

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An analytical study is presented that investigates the electrical impedance response of the ionic polymer transducer. Experimental studies have shown that the electromechanical response of these active materials is highly dependent upon internal parameters such as neutralizing counterion, diluent, electrode treatment, as well as environmental factors such as ambient temperature. Further examination has shown that these variations are introduced predominantly through the polymer's ability to convert voltage into charge migration. This relationship can easily be represented by the polymer's electrical impedance as measured across the outer electrodes of the transducer. In the first half of this study an analytical model is developed which predicts the time and frequency domain characteristics of the electrical response of the ionic polymer transducer. Transport equations serve as the basis for this model, from which a series of relationships are developed to describe internal potential, internal charge density, as well as surface current. In the second half of this study several analytical studies are presented to understand the impact that internal parameters have on the polymer's electrical response, while providing a conceptual validation of the model. In addition to the analytical studies several experimental comparisons are made to further validate the model by examining how well the model predicts changes in temperature, viscosity and pretention within the ionic polymer transducer.
机译:提出了一项分析研究,该研究调查了离子聚合物换能器的电阻抗响应。实验研究表明,这些活性材料的机电响应高度依赖于内部参数,例如中和抗衡离子,稀释剂,电极处理以及环境因素(例如环境温度)。进一步的研究表明,这些变化主要是由于聚合物将电压转换为电荷迁移的能力而引起的。这种关系可以很容易地由跨换能器外电极测量的聚合物电阻抗表示。在本研究的前半部分中,开发了一种分析模型,该模型可预测离子聚合物换能器电响应的时域和频域特性。输运方程式是该模型的基础,由此发展出一系列关系来描述内部电势,内部电荷密度以及表面电流。在本研究的后半部分,我们进行了一些分析研究,以了解内部参数对聚合物电响应的影响,同时提供模型的概念验证。除了分析研究之外,还进行了一些实验比较,以通过检查模型预测离子聚合物换能器内温度,粘度和保持力变化的程度来进一步验证模型。

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  • 来源
    《Journal of Applied Physics》 |2008年第1期|899-918|共20页
  • 作者单位
  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);
  • 原文格式 PDF
  • 正文语种 eng
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