Effect of multiple reflow on IMC formation using various surface finishes

摘要

In this paper, the results of a study on the effect of multiple reflow on the mechanism of intermetallic compounds (IMCs) formation of solder joints made from lead-free Sn-4Ag-0.5Cu (SAC405) on electroless nickel/electroless palladium/immersion gold (ENEP1G), electroless nickel/immersion gold (ENIG), immersion silver (ImAg) and copper surface finishes are presented. After the first reflow soldering, the well-known intermetallic Cu_6Sn_5 was observed in ImAg and Copper of surface finishes. While for ENEPIG and ENIG, mainly, (Ni,Cu)_3SNn_4 and (Cu,Ni)_6Sn_5 was formed respectively. By increasing the number of reflows up to three, the thickness of intermetallics increased gradually and their grain sizes coarsened. The intermetallics growth kinetics showed that the interfacial phase Cu_6Sn_5, (Ni,Cu)_3Sn_4 and (Cu,Ni)_6Sn_5 was controlled mainly by grain boundary diffusion and that the intermetallic growth on ENEPIG was found to be slowest among other surface finishes being used.