Studies on synthesis of plasma fusion relevant tungsten dust particles and measurement of their hydrogen absorption properties

摘要

In this communication, we identify some thermal-plasma assisted synthesis techniques for the alternative production of fusion relevant tungsten dust particles in bulk amounts, to allow for the statistically meaningful study of their hydrogen absorption properties. Fast, single step synthesis of fine particles in the alpha-tungsten phase was demonstrated, using a high heat flux device for sizes in the micrometer region and an experimental nanoparticle reactor for dust with nanometer sizes. Production of both equilibrium polyhedral and nonequilibrium spherulitic crystal shapes was demonstrated, dust morphologies similar to which were identified before in existing tokamaks and divertor simulator systems. Their hydrogen retention characteristics were measured by the Nuclear Resonance Reaction Analysis technique, which was found to be orders of magnitude higher compared to the same metal in the bulk form. The mesoporous crystals generated during high power, high pressure synthesis conditions were assumed to be responsible for the unusually high gas retention of the nanoparticle sample. It was concluded that non-equilibrium tungsten dust morphologies would be dominant in the high power fusion machines in the future, which may aggravate the hydrogen isotope retention issues further.