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Preparation of a kind of reactive pour point depressant and its action mechanism

机译:一种反应性降凝剂的制备及其作用机理

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摘要

A series of reactive pour point depressants (PPD) with anhydride group were prepared, and their action mechanism had been investigated by Fourier transform infrared spectroscopy (FTIR), differential scanning calorimeter (DSC) and cross-polarized light microscope. The results showed that the prepared pour point depressants had obvious pour point depressing effect on crude oil. Its action mechanism was concluded that PPD could react with the resin and asphaltene in the crude oil to generate a new macromol-ecule when crude oil was treated with PPD-3 at 90 ℃. The new macromolecule further formed a new agglomerate structure by association with the asphaltene and resin in crude oil, which worked as a new nucleator to provide nucleation sites for wax crystal instead of the original asphaltene-resin agglomerate structure, and then improved the flowability of crude oil.
机译:制备了一系列带有酸酐基的反应性降凝剂(PPD),并通过傅里叶变换红外光谱(FTIR),差示扫描量热仪(DSC)和交叉偏振光显微镜研究了它们的作用机理。结果表明,所制备的降凝剂对原油具有明显的降凝作用。结论其作用机理为:PPD-3在90℃处理时,PPD可与原油中的树脂和沥青质反应生成新的大分子分子。通过与原油中的沥青质和树脂结合,新的大分子进一步形成了新的团聚体结构,该新的大分子作为新的成核剂为蜡晶提供了成核位点,而不是原始的沥青质-树脂团聚体结构,从而提高了原油的流动性油。

著录项

  • 来源
    《Fuel》 |2015年第1期|448-454|共7页
  • 作者单位

    College of Chemical Engineering and Environmental, Qingdao University, Qingdao 266071, People's Republic of China;

    College of Chemical Engineering and Environmental, Qingdao University, Qingdao 266071, People's Republic of China;

    College of Chemical Engineering and Environmental, Qingdao University, Qingdao 266071, People's Republic of China;

    College of Chemical Engineering and Environmental, Qingdao University, Qingdao 266071, People's Republic of China;

  • 收录信息 美国《科学引文索引》(SCI);美国《工程索引》(EI);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

    Reactive; Pour point depressant; Agglomerate; Action mechanism;

    机译:反应性降凝剂;凝聚;动作机制;

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