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Molecular mobility and ageing of sugar glasses

机译:糖杯的分子迁移率和老化

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Carbohydrates play an important role in the stabilization of biological components under water stress and, consequently, in the preservation of foods. Water stress is produced either by freezing or drying producing damage in proteins and tissues mainly due to the generation of large gradients of concentration of salts. Some carbohydrates act as protectors but, although some explanations have been proposed, the mechanism is not yet properly known. We have measured the dielectric relaxation times of aqueous solutions of glucose in the time domain with a custom made device. Some results are presented here for a solution of glucose in water at 88% w/w, in the range of the glass transition temperature, including some data on the rubbery state (above T_g). The curves were fitted with a stretched exponential decay (KWW) with relaxation times in the range of 200-500s and stretching parameter (β) around 0.5.
机译:碳水化合物在水分胁迫下稳定生物成分中起着重要作用,因此在食品保存中也起着重要作用。水分胁迫是通过冷冻或干燥而产生的,这主要是由于盐浓度的大梯度的产生而在蛋白质和组织中造成损害。某些碳水化合物可以起到保护作用,但是尽管提出了一些解释,但其机制尚不完全清楚。我们已经使用定制设备在时域中测量了葡萄糖水溶液的介电弛豫时间。在玻璃化转变温度范围内,此处给出了88%w / w的葡萄糖水溶液的一些结果,包括一些橡胶态数据(高于T_g)。曲线拟合了舒张时间在200-500s范围内的拉伸指数衰减(KWW),拉伸参数(β)约为0.5。

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