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Effects of acrylonitrile content and hydrogenation on fatigue behaviour of HNBR

机译:丙烯腈含量和加氢对HNBR疲劳性能的影响

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The influence of acrylonitrile (ACN) content and hydrogenation on the fatigue properties of HNBR is investigated. HNBR blends consist of different quantities of acrylonitrile (24, 36, and 44 wt%) and per cent hydrogenation (91%, 96%, and 99%), and a composite of two blends of HNBR with 24 and 44 wt% ACN for an average of 36 wt% . A comprehensive experimental campaign is carried out with fatigue life and crack propagation testing at 120 degrees C. Afterwards, fatigue damage is analysed thanks to both optical and scanning electron microscopy. The results of the three experimental approaches demonstrate that HNBR with median ACN content (36 wt%) and median hydrogenation (96%) has the best fatigue resistance. In general, the fatigue resistance decreases in the following order: for ACN-36 to 44 to 24 wt%, and for hydrogenation-96% to 99% to 91%. The composite blend also has lower fatigue resistance than a regular HNBR blend.
机译:研究了丙烯腈(ACN)含量和加氢对HNBR疲劳性能的影响。 HNBR共混物由不同数量的丙烯腈(24、36和44 wt%)和加氢百分比(91%,96%和99%)组成,由HNBR的两种共混物与24和44 wt%的ACN组成平均为36 wt%。进行了全面的实验,并在120摄氏度下进行了疲劳寿命和裂纹扩展测试。此后,借助光学和扫描电子显微镜对疲劳损伤进行了分析。三种实验方法的结果表明,中值ACN含量(36 wt%)和中值氢化(96%)的HNBR具有最佳的抗疲劳性。通常,抗疲劳性按以下顺序降低:ACN-36为44至24 wt%,氢化为96%至99%至91%。与常规的HNBR共混物相比,该复合共混物还具有较低的抗疲劳性。

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