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A novel method for detection of camellia oil adulteration based on time-resolved emission fluorescence

机译:基于时间分辨发射荧光的山茶油掺假检测新方法

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In this study, time-resolved emission fluorescence (TRES) combined with chemometrics was developed and employed for adulteration analysis of camellia oil. TRES was first decomposed by parallel factors analysis (PARAFAC). Next, an artificial neural network (ANN) model was built for the adulteration analysis. A linear range of 5–50%, a limit of detection (LOD) of 3% and root mean square error of prediction ( RMSEP ) values lower than 3% were achieved. Compared with the steady-state measurement, easy access to the information from fluorophores of low concentration was shown to be an intrinsic advantage of the time-resolved measurement; this advantageous characteristic was helpful for optimizing adulteration analysis. It was demonstrated that TRES combined with chemometrics was a simple, rapid and non-intrusive method for adulteration analysis of vegetable oil.
机译:在这项研究中,时间分辨发射荧光(TRES)与化学计量学相结合,被开发并用于山茶油的掺假分析。 TRES首先通过并行因子分析(PARAFAC)进行分解。接下来,建立了一个人工神经网络(ANN)模型用于掺假分析。实现了5%至50%的线性范围,3%的检出限(LOD)和低于3%的预测均方根误差(RMSEP)值。与稳态测量相比,时间分辨测量的固有优势是易于访问低浓度荧光团的信息。这一有利特征有助于优化掺假分析。结果表明,TRES与化学计量学相结合是一种用于植物油掺假分析的简单,快速且非侵入性的方法。

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