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Low-Temperature Sintering Bonding Using Silver Nanoparticle Paste for Electronics Packaging

机译:电子封装用纳米银浆的低温烧结结合

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Ag nanoparticles (NPs) with about 40 nm diameter covered with 5–8 nm organic shell were prepared by chemical reduction reaction. The thermal characteristics of Ag nanoparticle (NP) paste were measured by thermogravimetric analysis (TGA) and differential scanning calorimetry (DSC). The low-temperature sintering bonding processes using Ag NP paste were carried out at the temperature range of 150–350°C for 5 min under the pressure of 3 MPa. The microstructures of the sintered joint and the fracture morphology were evaluated by scanning electron microscopy (SEM). The shear strength was used to evaluate the mechanical property of the sintered joint. TGA-DSC test showed that the Ag content is approximately 95.5 mass% in Ag NP paste. The average shear strength of the joint fabricated at 250°C for 5 min under the pressure of 3 MPa was about 28 MPa, which could meet the requirements of electronics packaging working at high temperature. The joint shear strength increased with the increase of the sintering temperature due to much denser sintered Ag NPs and more comprehensive metallurgical bonds formed in the joint.
机译:通过化学还原反应制备了直径约40 nm的被5-8 nm有机壳覆盖的银纳米颗粒(NPs)。通过热重分析(TGA)和差示扫描量热法(DSC)测量了银纳米颗粒(NP)浆料的热特性。使用Ag NP浆料的低温烧结粘结工艺是在3 MPa的压力下于150–350°C的温度范围内进行5 min。通过扫描电子显微镜(SEM)评估了烧结接头的微观结构和断裂形态。剪切强度用于评估烧结接头的机械性能。 TGA-DSC测试表明,在Ag NP糊剂中,Ag含量约为95.5质量%。在3 MPa的压力下于250°C焊接5 min制成的接头的平均剪切强度约为28 MPa,可以满足高温下电子封装的要求。接头的剪切强度随着烧结温度的升高而增加,这归因于烧结后的Ag NPs密度更高,接头中形成了更全面的冶金结合。

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