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Characterisation of olive fruit for the milling process by using visibleear infrared spectroscopy

机译:使用可见/近红外光谱表征用于研磨过程的橄榄果

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Increasing consumption of olive oil and table olives has recently determined an expansion of olive tree cultivation in the world. This trend is supported by the documented nutritional value of the Mediterranean diet. The aim of this work was to test a portable visible/ near infrared (vis/NIR) system (400-1000 nm) for the analysis of physical-chemical parameters, such as olive soluble solid content (SSC) and texture before the olive oil extraction process. The final goal is to provide the sector with post-harvest methods and sorting systems for a quick evaluation of important properties of olive fruit. In the present study, a total of 109 olives for oil production were analysed. Olive spectra registered with the optical device and values obtained with destructive analysis in the laboratory were analysed. Specific statistical models were elaborated to study correlations between optical and laboratory analysis, and to evaluate predictions of reference parameters obtained through the analysis of the visible-near infrared range. Statistical models were processed using chemometric techniques to extract maximum data information. Principal component analysis (PCA) was performed on vis/NIR spectra to examine sample groupings and identify outliers, while partial least square (PLS) regression algorithm was used to correlate samples spectra and physical- chemical properties. Results are encouraging. PCA showed a significant sample grouping among different ranges of SSC and texture. PLS models gave fairly good predictive capabilities in validation for SSC (R2=0.67 and RMSECV%=7.5%) and texture (R2=0.68 and RMSECV%=8.2%).
机译:橄榄油和食用橄榄的消费量增加,最近决定了世界范围内橄榄树种植的扩大。有记载的地中海饮食的营养价值支持了这一趋势。这项工作的目的是测试便携式可见/近红外(vis / NIR)系统(400-1000 nm),以分析理化参数,例如橄榄油之前的橄榄可溶性固形物(SSC)和质地提取过程。最终目标是为该部门提供收获后的方法和分类系统,以快速评估橄榄果的重要特性。在本研究中,总共分析了109个用于生产橄榄油的橄榄。分析了在光学设备中注册的橄榄光谱以及在实验室中通过破坏性分析获得的值。详细阐述了特定的统计模型,以研究光学分析与实验室分析之间的相关性,并评估通过对可见-近红外范围的分析获得的参考参数的预测。使用化学计量学技术处理统计模型以提取最大数据信息。对vis / NIR光谱执行主成分分析(PCA)以检查样品分组并识别离群值,同时使用偏最小二乘(PLS)回归算法来关联样品光谱和理化性质。结果令人鼓舞。 PCA在不同范围的SSC和纹理之间显示出显着的样本分组。 PLS模型在SSC(R2 = 0.67和RMSECV%= 7.5%)和纹理(R2 = 0.68和RMSECV%= 8.2%)的验证中提供了相当好的预测能力。

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