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A series of linear π conjugated arylene oligomers based on 1,5-naphthalene subunit: synthesis, characterization, and properties

机译:基于1,5-萘亚基的一系列线性π共轭亚芳基低聚物:合成,表征和性质

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摘要

A series of novel alkoxy-substituted arylene-ethynylene oligomers based on 1,5-naphthalene subunit have been successfully synthesized by palladium-catalyzed cross-coupling reaction. The solubility, thermal, optical, and electrochemical properties have been investigated in detail. The title compounds are soluble in common organic solvents and emit a blue color both in solution and in the solid state, indicating that these oligomers might serve as potential materials in optoelectronic devices.
机译:通过钯催化的交叉偶联反应,成功合成了一系列基于1,5-萘亚基的烷氧基取代的亚芳基-亚乙炔基低聚物。已对溶解度,热,光学和电化学性质进行了详细研究。标题化合物可溶于常见的有机溶剂,并且在溶液和固态下均呈蓝色,表明这些低聚物可能在光电器件中充当潜在材料。

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