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Physical Electrochemistry in the Undergraduate Curriculum: A Critical Assessment

机译:本科课程中的物理电化学:批判性评估

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The authors have analyzed the content of about a dozen physical chemistry textbooks regarded as among the most commonly used by undergraduate educators in the U.S. to identify the extent and quality of the material therein covered in the specific area of physical electrochemistry. It is recommended that the textbook writers should take advantage of material treated in its most fundamental forms, and find means to extend it to modern technological applications. Examples would include extensions of the Debye Hückel theory of electrolytes to interfacial charging of ideal polarizable electrodes, a concept that relates directly to the operation of electrochemical double layer capacitors as energy storage devices found in container port cranes around the globe. Also long overdue is the use of lithium ion batteries as examples that should replace the Weston or Daniell's voltaic piles, as well as the broad introduction of proton exchange membrane electrolyte based fuel cells instead of their historical liquid based predecessors. The copious resources of material available on the Web should be also used.
机译:作者分析了大约十二种物理化学教科书的内容,这些教科书被认为是美国大学生教育者最常使用的教科书,用于确定其中涵盖物理化学特定领域的材料的范围和质量。建议教科书作者应充分利用以最基本形式处理的材料,并找到将其扩展到现代技术应用的方法。例子包括将电解质的德拜·休克尔理论扩展到理想的可极化电极的界面充电,这一概念直接涉及电化学双层电容器作为全球集装箱港口起重机中的储能设备的运行。早就应该使用锂离子电池来代替Weston或Daniell的伏堆,以及大量引入基于质子交换膜电解质的燃料电池,而不是其历史上基于液体的前身。还应使用网上可用的大量资源。

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