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(3Z)-5-Chloro-3-(hy-dr-oxy-imino)-indolin-2-one

机译:(3Z)-5-氯-3-(氢-氧-亚氨基)-吲哚-2-

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In the title compound, C8H5ClN2O2?(common name: 5-chloro-isatin 3-oxime), the mol-ecular structure deviates slightly from the ideal planarity, with a maximum deviation of 0.0478?(8)?? for the non-H atoms. In the crystal, mol-ecules are linked by N—H?O inter-actions, building centrosymmetric dimers with graph-set motif?R22(8). Additionally, the mol-ecules are connected by pairs of O—H?O inter-actions into chains along [100] with a?C(6) motif. The hydrogen-bonded dimers and chains build a two-dimensional network parallel to (100). The packing also features?π–π?stacking inter-actions between benzene rings [centroid–centroid distance = 3.748?(2)??].
机译:在标题化合物C8H5ClN2O2(通用名称:5-氯-isatin 3-肟)中,分子结构与理想的平面度略有偏离,最大偏差为0.0478?(8)?对于非氢原子在晶体中,mol-ecule通过N-H2O相互作用连接,从而建立具有图集基序R22(8)的中心对称二聚体。另外,该分子通过成对的O-H2O相互作用沿[100]沿着带有aC(6)主题的链连接。氢键合的二聚体和链建立一个平行于(100)的二维网络。填料还具有苯环之间的π-π堆积相互作用[质心-质心距离= 3.748?(2)?]。

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