High Density Solvent Based Dispersive Liquid-Liquid Microextraction Technique for Simultaneous and Selective Extraction of Multiclass Pesticide Residues in Water and Sugarcane Juice Samples

摘要

In this study, a miniaturized analytical technique based on high density solvent based dispersive liquid-liquid microextraction (HD-DLLME) was developed for extraction of trace residues of multiclass pesticides including three striazine herbicides, two organophosphate insecticides and two organochlorine fungicides from environmental water and sugarcane juice samples. The analytical method was validated and found to offer good linearity: R2 ≥ 0.991; repeatability varied from 0.73% - 5.28%; reproducibility varied from 1.14% - 8.74% and limit of detection ranged from 0.005 to 0.02 μg/L. Moreover, accuracy of the optimized method was evaluated and the recovery was varied from 80.39% - 114.05%. Analytical applications of this method to environmental waters and sugarcane juice samples indicate the presence of trace residues of ametryn in the lake water and sugarcane juice samples. Atrazine and ametryn were also detected in irrigation water.