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Acid-catalysed direct transformation of cellulose into methyl glucosides in methanol at moderate temperatures

机译：在中等温度下，酸催化甲醇将纤维素直接转化为甲基葡糖苷

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摘要

Cellulose can be transformed into methyl glucosides in methanol with yields of 50-60% in the presence of several acid catalysts under mild conditions (≤473 K); H_3PW_(12)O_(40) provides the highest turnover number (～73 in 0.5 h) for the formation of methyl glucosides among many acid catalysts examined.
机译：在温和的条件下（≤473K），在几种酸催化剂的存在下，纤维素可以在甲醇中转化为甲基葡萄糖苷，收率为50-60％；在许多检测到的酸催化剂中，H_3PW_（12）O_（40）为形成甲基葡糖苷提供了最高的转换数（0.5小时内〜73）。

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  • 来源
    《Chemical Communications》 |2010年第15期|p.2668-2670|共3页
  • 作者

    Weiping Deng; Mi Liu; Qinghong Zhang; Xuesong Tan; Ye Wang;

  • 作者单位

    State Key Laboratory of Physical Chemistry of Solid Surfaces,National Engineering Laboratory for Green Chemical Productions of Alcohols, Ethers and Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China;

    State Key Laboratory of Physical Chemistry of Solid Surfaces,National Engineering Laboratory for Green Chemical Productions of Alcohols, Ethers and Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China;

    State Key Laboratory of Physical Chemistry of Solid Surfaces,National Engineering Laboratory for Green Chemical Productions of Alcohols, Ethers and Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China;

    State Key Laboratory of Physical Chemistry of Solid Surfaces,National Engineering Laboratory for Green Chemical Productions of Alcohols, Ethers and Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China;

    State Key Laboratory of Physical Chemistry of Solid Surfaces,National Engineering Laboratory for Green Chemical Productions of Alcohols, Ethers and Esters, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China;

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