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Oxidation of benzylic compounds by gold nanowires at 1 atm O_2

机译:金纳米线在1 atm O_2处氧化苄基化合物

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摘要

Ultra-thin gold nanowires (GNWs), with uniform surface crystallinity, appear much more active than gold nanoclusters in benzylic compound oxidation. Ethylbenzene oxidation was used as a model reaction and a radical chain reaction mechanism was revealed by the DFT method.
机译:具有均匀表面结晶度的超薄金纳米线(GNW)在苄基化合物氧化中似乎比金纳米团簇更具活性。使用乙苯氧化作为模型反应,并通过DFT方法揭示了自由基链反应机理。

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  • 来源
    《Chemical Communications》 |2011年第4期|p.1303-1305|共3页
  • 作者单位

    ey Laboratory of Organic Synthesis of Jiangsu Province, Key Laboratory of Absorbent Materials and Techniques for Environment,College of Chemistry, Chemical Engineering and Materials Science,Soochow University, Suzhou, 215123, China;

    ey Laboratory of Organic Synthesis of Jiangsu Province, Key Laboratory of Absorbent Materials and Techniques for Environment,College of Chemistry, Chemical Engineering and Materials Science,Soochow University, Suzhou, 215123, China;

    Institute of Materials Technology & Engineering,Chinese Academy of Sciences, Ningbo, 315201, China;

    ey Laboratory of Organic Synthesis of Jiangsu Province, Key Laboratory of Absorbent Materials and Techniques for Environment,College of Chemistry, Chemical Engineering and Materials Science,Soochow University, Suzhou, 215123, China;

    ey Laboratory of Organic Synthesis of Jiangsu Province, Key Laboratory of Absorbent Materials and Techniques for Environment,College of Chemistry, Chemical Engineering and Materials Science,Soochow University, Suzhou, 215123, China;

    ey Laboratory of Organic Synthesis of Jiangsu Province, Key Laboratory of Absorbent Materials and Techniques for Environment,College of Chemistry, Chemical Engineering and Materials Science,Soochow University, Suzhou, 215123, China;

    ey Laboratory of Organic Synthesis of Jiangsu Province, Key Laboratory of Absorbent Materials and Techniques for Environment,College of Chemistry, Chemical Engineering and Materials Science,Soochow University, Suzhou, 215123, China;

    ey Laboratory of Organic Synthesis of Jiangsu Province, Key Laboratory of Absorbent Materials and Techniques for Environment,College of Chemistry, Chemical Engineering and Materials Science,Soochow University, Suzhou, 215123, China;

    ey Laboratory of Organic Synthesis of Jiangsu Province, Key Laboratory of Absorbent Materials and Techniques for Environment,College of Chemistry, Chemical Engineering and Materials Science,Soochow University, Suzhou, 215123, China;

    Institute of Materials Technology & Engineering,Chinese Academy of Sciences, Ningbo, 315201, China;

    ey Laboratory of Organic Synthesis of Jiangsu Province, Key Laboratory of Absorbent Materials and Techniques for Environment,College of Chemistry, Chemical Engineering and Materials Science,Soochow University, Suzhou, 215123, China;

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  • 入库时间 2022-08-17 13:22:05

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