Enhanced photocurrent production from thin films of Ru(Ⅱ) metallopoly mer/Davvson polyoxotungstate adducts under visible irradiation

James J. Walsh; Colm T. Mallon; Alan M. Bond; Tia E. Keyes; Robert J. Forster

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Enhanced photocurrent production from thin films of Ru(Ⅱ) metallopoly mer/Davvson polyoxotungstate adducts under visible irradiation

机译：可见光照射下Ru（Ⅱ）金属多聚体/ Davvson多氧钨酸盐加合物薄膜增强光电流产生

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Thin films of polyoxometalates that are sensitized with a Ru(Ⅱ) metallopolymer generate significant photocurrents in the presence of benzyl alcohol and visible light. Significantly, the photocurrent generated by the tungstate based adduct, α-[P_2W_(18)O_(62)]~(6-), is approximately seven fold larger than that found for the Dawson polyoxomolybdate α-[S_2Mo_(18)O_(62)]~(4-).

机译：在苯甲醇和可见光存在下，用Ru（Ⅱ）金属聚合物敏化的多金属氧酸盐薄膜会产生明显的光电流。明显地，基于钨酸盐的加合物α-[P_2W_（18）O_（62）]〜（6-）产生的光电流比道森多氧钼酸盐α-[S_2Mo_（18）O_（ 62）]〜（4-）。

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《Chemical Communications》 |2012年第30期|p.3593-3595|共3页
作者
James J. Walsh; Colm T. Mallon; Alan M. Bond; Tia E. Keyes; Robert J. Forster;
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School of Chemical Sciences, National Centre for Sensor Research,Dublin City University, Glasnevin, Dublin 9, Ireland;

School of Chemical Sciences, National Centre for Sensor Research,Dublin City University, Glasnevin, Dublin 9, Ireland;

School of Chemistry, Monash University, Clayton, Victoria 3800,Australia;

School of Chemical Sciences, National Centre for Sensor Research,Dublin City University, Glasnevin, Dublin 9, Ireland;

School of Chemical Sciences, National Centre for Sensor Research,Dublin City University, Glasnevin, Dublin 9, Ireland;

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Enhanced photocurrent production from thin films of Ru(Ⅱ) metallopoly mer/Davvson polyoxotungstate adducts under visible irradiation

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