Spontaneous transformation from micelles to vesicles associated with sequential conversions of comprising amphiphiles within assemblies

Katsuto Takakura; Takahiro Yamamoto; Kensuke Kurihara; Taro Toyota; Kiyoshi Ohnuma; Tadashi Sugawara

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Spontaneous transformation from micelles to vesicles associated with sequential conversions of comprising amphiphiles within assemblies

机译：从胶束到囊泡的自发转化与组装物中包含两亲物的顺序转化有关

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摘要

A morphological transformation from hybrid micelles to giant vesicles was observed in aqueous dispersion associated with formation of a double-chained amphiphile as a result of the migration of dodecylamine from the amphiphilic imine to the amphiphilic aldehyde within the hydrophobic environment of amphiphilic aggregates.

机译：在两亲性聚集体的疏水环境中十二烷基胺从两亲亚胺向两亲醛的迁移，在与双链两亲物形成相关的水分散体中观察到了从杂化胶束向大囊泡的形态转化。

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《Chemical Communications》 |2014年第17期|2190-2192|共3页
作者
Katsuto Takakura; Takahiro Yamamoto; Kensuke Kurihara; Taro Toyota; Kiyoshi Ohnuma; Tadashi Sugawara;
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Department of Chemistry and Biochemistry, Suzuka National College of Technology, Shiroko-cho, Suzuka, Mie 510-0294, Japan;

Department of Chemistry and Biochemistry, Suzuka National College of Technology, Shiroko-cho, Suzuka, Mie 510-0294, Japan;

Department of Bask Science, Graduate School of Arts and Sciences, The University of Tokyo, 3-8-1 Komaba, Meguro-ku, Tokyo 153-8902, Japan;

Department of Bask Science, Graduate School of Arts and Sciences, The University of Tokyo, 3-8-1 Komaba, Meguro-ku, Tokyo 153-8902, Japan,Research Center for Complex Systems Biology, The University of Tokyo, 3-8-1 Komaba, Meguro-ku, Tokyo 153-8902, Japan;

Top Runner Incubation Center for Academia-Industry Fusion, Nagaoka University of Technology, 1603-1 Kamitomioka-cho, Nagaoka, Niigata 940-2188, Japan;

Research Center for Complex Systems Biology, The University of Tokyo, 3-8-1 Komaba, Meguro-ku, Tokyo 153-8902, Japan,Department of Chemistry, Faculty of Science, Kanagawa University, 2946 Tsuchiya, Hiratsuka, Kanagawa 259-1293, Japan;

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1. Self-assembly in a catanionic mixture with an aminoacid-derived surfactant: From mixed micelles to spontaneous vesicles [J] . Brito RO, Marques EF, Gomes P, The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical . 2006,第37期

机译：与氨基酸衍生的表面活性剂在阳离子混合物中的自组装：从混合胶束到自发囊泡
2. Self-assembly in a catanionic mixture with an aminoacid-derived surfactant: From mixed micelles to spontaneous vesicles [J] . Brito RO, Marques EF, Gomes P, The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical . 2006,第37期

机译：与氨基酸衍生的表面活性剂在阳离子混合物中的自组装：从混合胶束到自发囊泡
3. Binary-component micelle and vesicle: Free energy and asymmetric distributions of amphiphiles between vesicle monolayers [J] . Zhang Qi-Yi, Xiang Xun 中国物理：英文版 . 2013,第003期

机译：二元组分胶束和囊泡：囊泡单层之间的两性自由能和不对称分布
4. Self Assembly of Peptide Amphiphiles into Bilayers and Micelles: Physical Properties and Applications [C] . Matthew Tirrell, Badriprasad Ananathanarayanan, Mark Kastantin PMSE Symposia . 2009

机译：将肽两亲物组装成双层和胶束：物理性质和应用
5. Electrostatically Driven Assembly of Charged Amphiphiles Forming Crystallized Membranes, Vesicles and Nanofiber Arrays. [D] . Leung, Cheuk Yui Curtis. 2013

机译：带电两亲物的静电驱动组装，形成结晶的膜，囊泡和纳米纤维阵列。
6. Curvature-coupled hydration of Semicrystalline Polymer Amphiphiles yields flexible Worm Micelles but favors rigid Vesicles: polycaprolactone-based block copolymers [O] . Karthikan Rajagopal, Abdullah Mahmud, David A. Christian, -1

机译：半结晶聚合物两亲物的曲率耦合水合产生柔性蠕虫胶束但有利于刚性囊泡：基于聚己内酯的嵌段共聚物
7. Self-Assembly in a Catanionic Mixture with an Aminoacid-Derived Surfactant: From Mixed Micelles to Spontaneous Vesicles [O] . -1

机译：用氨基酸衍生的表面活性剂的氨基酸衍生的表面活性剂自组装：从混合胶束到自发囊泡
8. Chemical and Photochemical Reactions of Porphyrins and Metalloporphyrins in Micelles, Vesicles, Films, Monolayer Assemblies and Solution [R] . Whitten, D. G. 1984

机译：卟啉和金属卟啉在胶束，囊泡，薄膜，单层组件和溶液中的化学和光化学反应

Spontaneous transformation from micelles to vesicles associated with sequential conversions of comprising amphiphiles within assemblies

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