On the importance of steady-state isotopic techniques for the investigation of the mechanism of the reverse water-gas-shift reaction

Daniele Tibiletti; Alexandre Goguet; Frederic C. Meunier; John P. Breen; Robbie Burch

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On the importance of steady-state isotopic techniques for the investigation of the mechanism of the reverse water-gas-shift reaction

机译：稳态同位素技术在研究逆水煤气变换反应机理中的重要性

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The formation and reactivity of surface intermediates in the reverse water-gas-shift reaction on a Pt/CeO_2 catalyst are critically dependent on the reaction conditions so that conclusions regarding the reaction mechanism cannot be inferred using ex operando conditions.

机译：在Pt / CeO_2催化剂上进行逆水煤气变换反应中表面中间体的形成和反应性严重依赖于反应条件，因此无法使用操作条件得出关于反应机理的结论。

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来源
《Chemical Communications》 |2004年第14期|p. 1636-1637|共2页
作者
Daniele Tibiletti; Alexandre Goguet; Frederic C. Meunier; John P. Breen; Robbie Burch;
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作者单位

CenTACat, School of Chemistry, Queen's University Belfast, Belfast, Northern Ireland BT41 1PB;

CenTACat, School of Chemistry, Queen's University Belfast, Belfast, Northern Ireland BT41 1PB;

CenTACat, School of Chemistry, Queen's University Belfast, Belfast, Northern Ireland BT41 1PB;

CenTACat, School of Chemistry, Queen's University Belfast, Belfast, Northern Ireland BT41 1PB;

CenTACat, School of Chemistry, Queen's University Belfast, Belfast, Northern Ireland BT41 1PB;

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正文语种 eng
中图分类化学;
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入库时间 2022-08-17 13:33:11

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1. On the need to use steady-state or operando techniques to investigate reaction mechanisms:An in situ DRIFTS and SSITKA-based study example [J] . Daniele Tibiletti, Alexandre Goguet, David Reid, Catalysis Today . 2006,第1a2期

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机译：关于Pt / CeO2催化剂上水煤气变换反应机理的复杂性：温度对化学稳态同位素瞬态过程中操作DRIFT研究的温度对甲酸表面物种反应性的影响
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7. Spectrokinetic investigation of reverse water-gas-shift reaction intermediates over a Pt/CeO2 catalyst [O] . Goguet Alexandre, Tibiletti Daniele, Meunier Frederic, 2004

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On the importance of steady-state isotopic techniques for the investigation of the mechanism of the reverse water-gas-shift reaction

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