Synthesis of nano-TiO2/diatomite composite and its photocatalytic degradation of gaseous formaldehyde

摘要

The TiO2/diatomite composite was synthesized through a mild hydrolysis of titanyl sulfate. The prepared composite was characterized by X-ray diffraction, N-2 adsorption-desorption, scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy and UV-vis diffused reflectance spectroscopy. The results demonstrate that the anatase TiO2 nanopartilces anchored on the surface of diatomite with Ti-O-Si bonds between diatomite and TiO2. The photodegradation of gaseous formaldehyde under UV irradiation by the TiO2/diatomite composite was studied under various operating conditions, including relative humidity, illumination intensity and catalyst amount, which have significant influence on the degradation process. The TiO2/diatomite composite exhibited better photocatalytic activity than pure TiO2, which could be attributed to the favorable nanoparticles dispersibility and strong formaldehyde adsorption capacity. In addition, the composite exhibited outstanding reusability over five cycles. The TiO2/diatomite composite shows great promising application foreground in formaldehyde degradation. (C) 2017 Elsevier B.V. All rights reserved.